Table 3.
BET analysis results of lignin-based porous carbon materials by activation conditions
Activation source | Sample | SBETa | daveb | Vmicroc | Vmesod | Vtotale | Vmicro/Vtotalf | Yieldg |
- | LBPC | 45.8 | 2.38 | 0.02 | 0.17 | 0.19 | 0.1053 | - |
KOH | KA-LBPC-6 | 1017.9 | 1.81 | 0.37 | 0.09 | 0.46 | 0.8043 | 80 |
KA-LBPC-7 | 2480.1 | 2.26 | 0.64 | 0.76 | 1.40 | 0.4571 | 72 |
KA-LBPC-8 | 1192.2 | 1.89 | 0.44 | 0.12 | 0.56 | 0.7857 | 64 |
KA-LBPC-9 | 666.5 | 2.72 | 0.14 | 0.31 | 0.45 | 0.3111 | 35 |
: specific surface area (m2/g)
: mean pore diameter (nm)
: micropore volume (cm3/g)
: mesopore volume (cm3/g)
: total pore volume (cm3/g)
: micropore fraction to total pore volume
: yield of LBPC after activation (%)
LBPC: non-activated and carbonized Lignin-PAN copolymer
KA-LBPC-x: KOH activated and carbonized Lignin-PAN copolymer